Yes. You will be able to use a Western Union Prepaid MasterCard to pay bills, just like a credit card or a debit card. The card also offers online bill payment via online account. Once you are cardholder, you will be able to see bill payment options as well as fees through online account center provided and serviced by NetSpend.
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All rates and fees, and other terms and conditions of the products mentioned in this article/post are actual as of the last update date but are subject to change. See the current products' Terms & Conditions on the issuing banks' websites.