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Pottery Barn card is a store credit card that is not affiliated with any major payment network. So it can only be used at Pottery Barn stores. If you want your credit card to be accepted everywhere (including Pottery Barn locations), you should apply for a general credit card with rewards. You may choose rewards program according to your needs - cash back, miles or points.
If you want a cash back credit card to use at any store, you should consider the Discover it® Cash Back card. The card offers 1% cash back on all purchases. You can even get 5% cash back if you enroll in rotating categories every quarter (up to the quarterly maximum).