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Unfortunately, the Mercedes-Benz credit card is no longer issued, and you can't apply for it. Only current cardholders can still use the card and earn rewards. however, there are still options for receiving points for Mercedes-Benz purchases - general rewards credit cards. These cards will reward you for any purchase made with the card, and the rewards never expire.
For example, the Discover it® Cash Back credit card offers 5% cash back on purchases in selected categories that change each quarter (up to the quarterly maximum and you need to activate these categories). You will earn 1% cash back on all other purchases. At the end of the first year of card usage Discover will match all the rewards you've earned if you are a new cardmember.